Low current plasmatron fuel converter having enlarged volume discharges

ABSTRACT

A novel apparatus and method is disclosed for a plasmatron fuel converter (“plasmatron”) that efficiently uses electrical energy to produce hydrogen rich gas. The volume and shape of the plasma discharge is controlled by a fluid flow established in a plasma discharge volume. A plasmatron according to this invention produces a substantially large effective plasma discharge volume allowing for substantially greater volumetric efficiency in the initiation of chemical reactions within a volume of bulk fluid reactant flowing through the plasmatron.

GOVERNMENT SUPPORT

This invention was made with government support under Grant Nos.DE-AC03-99EE50565 and DE-FG04-95AL88002 , awarded by the Department ofEnergy. The United States Government has certain rights in theinvention.

FIELD OF THE INVENTION

The present invention relates to a method and apparatus for a plasmafuel converter and more particularly to a low current plasmatron fuelconverter having enlarged volume discharges.

BACKGROUND OF THE INVENTION

Plasmatron fuel converters reform hydrocarbons to generate a hydrogenrich gas through the use of plasma discharges. (See, for example, U.S.Pat. Nos. 6,322,757 and 5,887,554, the teachings of which areincorporated herein by reference). Two general types of plasma dischargeregimes can be distinguished by their electrical characteristics andtheir modes of operation. A non-arcing discharge regime operates at highvoltage and low currents, while an arc discharge regime operates at lowvoltage and high currents. (For a general treatise, see J. Reece Roth,Industrial Plasma Engineering, Vol. 1 and 2, Institute of Physics:Bristol, UK, 1995).

Thermal arc plasmatrons have received particular attention in the priorart. (See, for example, U.S. Pat. Nos. 5,425,332 and 5,437,250, theteachings of which are incorporated herein by reference). These thermalarc plasmatrons operate at low voltage and high current and, therefore,have relatively inefficient electrical power to chemical powerconversion ratios. Better electrical power to chemical power conversionratios, as well as lower current resulting in lower electrode erosion,can be obtained through the use of non-arcing discharge plasmatrons.However, non-arcing discharges are usually operable at sub-atmosphericpressure, typically less than about 20 Torr. When pressure is increased,the non-arcing discharge rapidly transitions to an arc discharge. Lowpressure gas glow discharges and apparatus for their production areknown. (See, for example, U.S. Pat. Nos.: 2,787,730; 3,018,409;3,035,205; 3,423,562; 4,830,492; 4,963,792; and 4,967,118, the teachingsof which are incorporated herein by reference). However, the effectivevolumetric flow rates through these low pressure devices are limited.

It is desirable to have a plasma converter that produces discharges inthe non-arcing regime in a substantially continuous manner with asubstantially enlarged effective discharge volume.

SUMMARY OF THE INVENTION

A novel apparatus and method is disclosed for a plasmatron fuelconverter (“plasmatron”) that efficiently uses electrical energy toproduce hydrogen rich gas. The volume and shape of the plasma dischargeis controlled by a fluid flow established in a plasma discharge volume.A plasmatron according to this invention produces a substantially largeeffective plasma discharge volume allowing for substantially greatervolumetric efficiency in the initiation of chemical reactions within avolume of bulk fluid reactant flowing through the plasmatron.

In one aspect, the invention is a plasmatron fuel converter comprising afirst electrode and a second electrode separated from the firstelectrode by an electrical insulator and disposed to create a gap withrespect to the first electrode so as to form a discharge volume adaptedto receive a fuel/air mixture. A power supply is connected to the firstand second electrodes and adapted to provide voltage and currentsufficient to generate a plasma discharge within the discharge volume.Fluid flow is established in the discharge volume so as to stretch anddeform the plasma discharge.

BRIEF DESCRIPTION OF THE DRAWING

The invention is described with reference to the several figures of thedrawing, in which:

FIG. 1 is a cross-sectional view of a low current, low power plasmatronfuel converter according to one embodiment of the invention;

FIG. 2 is a cross-sectional view of a plasmatron fuel converterillustrating a combined flow of a fuel/air mixture and plasma shapingair;

FIG. 3 is a cross-sectional view of a plasmatron fuel converter with aturbulizer according to one embodiment of the invention;

FIG. 4 is a cross-sectional view of a plasmatron fuel converter showingthe use of hot recirculated hydrogen rich gas according to oneembodiment of the invention; and

FIG. 5 is a cross-sectional view of a plasmatron fuel converter with aheat exchanger according to one embodiment of the invention; and

FIGS. 6A-6C are cross-sectional views of multiple electrodeconfigurations according to multiple embodiments of the invention.

DETAILED DESCRIPTION OF THE INVENTION

Robust, large volume plasma discharges are needed for fast start-up oflow current, low power plasmatron fuel converters (“plasmatrons”) andfor efficient operation after start-up. Efficient operation requiresboth the efficient use of electrical energy to promote chemicalreactions in a given discharge volume and volumetric efficiency in thepercentage of chemical conversion achieved in the volume of bulkreactant fluid. Such efficient operation has been achieved by thepresent invention through the use of a plasmatron having a specialconfiguration which utilizes a low current plasma discharge that iscontinually stretched and extinguished by flowing gas and is thenquasi-instantly and randomly reestablished elsewhere in the dischargevolume. Importantly, the chemical effects of the active species flux inthe region of the bulk fluid local to an extinguished dischargetypically persist for a much greater period than the cycle period of anindividual plasma discharge. This continual and rapid displacement ofthe discharge from one path in the discharge region to another coversboth a relatively large area perpendicular to the flow of injectedreactant fluids and a significant distance along the flow. Rapidestablishment, extinction and reestablishment of the plasma discharges,combined with initiation of persistent chemical reactions by the flux ofactive species generated by the discharge, result in a quasi-continuousplasma discharge. The quasi-continuous plasma discharge effectivelyfills the discharge volume and initiates chemical reactions throughoutthat volume.

The efficiency of the plasmatron in use of electrical energy to promotehydrogen producing reactions is determined, in part, by the ratio of theperiod of operation in the non-arcing discharge regime to the totalperiod of plasma discharge during an average cycle of operation. Thus,the plasmatron of this invention can operate in a substantiallycontinuous manner in the non-arc discharge regime.

One preferred embodiment of the invention is as a fast starting, lowcurrent, low power enlarged volume plasmatron. One application involvespartial oxidation of hydrocarbon fuels to produce hydrogen rich fuelsfor use in internal combustion systems such as gasoline or dieselengines and their associated exhaust systems. Such plasmatrons may beselected for operation between stoichiometric partial oxidation and fullcombustion depending on conditions and applications. During fullcombustion, the output of the plasmatron is a hot gas that is no longerhydrogen-rich. Operation in full combustion is generally only maintainedfor brief periods. Power for operation of the plasmatron will preferablybe provided by components of the internal combustion system.

Referring now to the figures of the drawing, the figures constitute apart of this specification and illustrate exemplary embodiments to theinvention. It is to be understood that in some instances various aspectsof the invention may be shown exaggerated or enlarged to facilitate anunderstanding of the invention.

FIG. 1 is a cross-sectional view of one embodiment for a low current,low power plasmatron 10. In a preferred embodiment, fuel 12 and oxidant(e.g. air) 14 are supplied to the plasmatron 10 to form a fuel-airmixture 16. Alternatively, the reactive mixture 16 supplied to theplasmatron 10 may comprise only atomized fuel (without oxidant). In apreferred embodiment that maximizes volume and minimizes electrode wear,the plasmatron is comprised of a top cylindrical electrode 20 and abottom cylindrical electrode 24 separated by an electrical insulator 22.This cylindrical geometry minimizes average current density andassociated erosion on the surface of both electrodes 20, 24. Inadvertentor excessive operation in the arc discharge regime, and its associatedwear on the surface of the electrodes 20, 24, may be minimized byincluding a current limiting feature in a high voltage power supply 18attached to the electrodes 20, 24. The electrodes 20, 24 are axiallyaligned with the longitudinal axis of the plasmatron 10 allowing for agap in between them to form a plasma discharge volume 26 by at least twoboundaries. An additional fluid flow (e.g. air or a fuel/air mixture) 19is introduced into the plasma discharge volume 26 with a tangentialcomponent to produce a flow that stretches, deforms and moves poloidallythe discharge. This plasma shaping air (or air/fuel) 19 may beestablished by one or more apertures (or channels) 28 between the topand bottom electrodes. These apertures may be designed to provide avorticity to the plasma shaping air as it flows through the plasmadischarge volume 26.

In one embodiment, the flow of the fuel/air mixture 16 and the flow ofthe plasma shaping air 19 are perpendicular to one another. Establishingthe flows in this manner through the discharge volume maximizes theeffective volume of the bulk fuel/air mixture 16 and plasma shaping air19 that interact with the volume of active species from the plasmadischarges. These active species are within each plasma discharge andwithin the regions of the bulk fuel/air mixture 16 local to each plasmadischarge. This geometry can provide continual initiation of the partialoxidation reactions at all sub-volumes of plasma discharge volume 26radial to the axis of the flow of the fuel/air mixture 16. Therelatively long paths of plasma discharges along the main direction offlow ensures adequate reaction initiation at multiple radial and axialpositions, thus assuring efficient ignition. Where conditions, such aslow oxygen/fuel ratios, limit the persistence and propagation of partialoxidation reactions (i.e. limited or quenched “flame” or “ignition”propagation), reaction initiation at multiple radial and axial positionsalong the axis of flow ensures reaction initiation in the fuel/airmixture 16 throughout the plasma discharge volume 26.

In a preferred embodiment, the liquid fuel 12 is atomized and introducedfrom the center of the top electrode 20. Fuel atomization can beachieved by appropriate nozzle 21 design, with or without air assist.When operating with liquid hydrocarbons, fuel deposition andcondensation on the inner surfaces of electrodes 20, 24 may be reducedby employing the nozzle 21 to produce a narrow jet of fuel droplets.Spray angles between 15 and 30 degrees have been shown to be sufficient.

The plasma discharge is established by supplying high voltage (300 V to60 kV) (and resulting current in the range of approximately 10milliamperes to 2 amperes) in the discharge volume 26 between electrodes20, 24. The plasma shaping air 19 is injected from a side aperture 28 insuch a way as to create shear and displacement stresses that deform anddisplace the volume of the plasma discharge (and plasma sheath, if any)and mix the the fuel/air mixture 16 with the plasma discharge. Thestresses stretch and deform the discharge, thus affecting the electricaland thermal characteristics of the plasma. If stretched beyond acritical length, the plasma's electrical field becomes unsustainable.Whether in thermodynamic equilibrium or non-equilibrium, the low currentnon-arcing discharge is eventually elongated to the point of extinctiondue to current limitation, voltage limitation or geometric plasmainstability.

The plasma discharge is reestablished almost instantaneously along adifferent pathway between two random points on the electrodes 20, 24.The plasma discharge is generally restablished in a time of less than100 nanoseconds. Depending on the selections of various operationalparameters of the plasmatron, this process occurs naturally at a highfrequency of plasma discharge initiation and extinction and providesquasi-uniform plasma discharge throughout the entire volume of thedischarge region. The frequency of plasma discharge initiation andextinction is here termed ‘cycle frequency’. Natural cycle frequency fora plasmatron fuel converter of the illustrated preferred embodiment willtypically be on the order of several kHz (1-10 kHz). Since the chemicalreactions initiated by each individual discharge persist and propagatein the region of the bulk fuel/air mixture 16 local to the discharge fora significant time after the extinction of the discharge, the effect ofthe quasi-uniform, ‘volumetric’ plasma discharge is to produce avolumetric initiation (‘volumetric ignition’) of chemical reactionsthroughout the bulk fuel/air mixture 16.

Generally, the plasmatron will provide average power to the plasma inrange of between 10 and 1000 watts. The electrical power consumption isgenerally between 0.3% to 10% of the thermal power content of thehydrogen rich gas produced by the plasmatron.

The cycle frequency necessary to provide a quasi-uniform plasmadischarge can be provided by the selection of various electrical andfluid dynamic characteristics of the plasmatron as described above.Generally, the power supply frequency will be adjusted in the range of100 Hz to 2 MHz. By controlling the electrical and thermodynamicparameters of the plasma, the operation of this plasmatron fuelconverter can be selected for high energy conversion efficiency and forselectivity in the chemical processes initiated by the volumetricignition. In the preferred embodiment of the invention, such selectivityis for the production of hydrogen gas from hydrocarbon fuel.

The combination of volumetric ignition and high turbulence of thefuel/air stream is a very important feature of fast start fuelreforming. The enlarged volumetric discharge maximizes plasma andfuel/air mixture 16 contact and ensures initiation of the reactionthroughout this mixture. By careful selection of the operatingparameters of the air 14 and the fuel 12, and with the turbulenceprovided by the plasma and the fluid flow, the conditions for optimalchemical reactions are achieved. The air-fuel ratio, and thus theoxygen—carbon (O/C) ratio, can be varied from as low as an O/C ratio=1for stoichiometric partial oxidation to as high as an O/C ratios=2 forliquid hydrocarbon fuels with a composition of (CH₂)_(n), and preferablythe O/C ratio will be in the range of 1.0 to 1.2. The volumetricignition feature of the present application is very useful in achievinghigh volumetric efficiencies and high electrical efficiencies underconditions of reduced chemical reaction persistence and/or propagation.Such conditions occur in very fuel rich environments characteristic ofpartial oxidation reformation of hydrocarbon fuel, where chemicalinitiation at any individual site in the discharge volume is difficultto initiate and maintain because of very slow ‘flame’ propagation speed.

Following quasi-uniform volumetric ignition in the discharge region, anignited fuel/air stream 29 is introduced into a reactor 30 having areaction extension cylinder or region 32. The reactor 30 includes asteel tube 34 with inner thermal insulation 36 and outer thermalinsulation 38. The reactor 30 may have a catalytic structure 40 at thebottom. The preferable catalytic structure 40 is a ceramic or metallichoneycomb support coated with rare metals (e.g. Pt, Pd). The honeycombconfiguration has a low thermal mass which facilitates fast start.

In a preferred embodiment, the reaction extension region 32 provides agap between the exit of the bottom electrode 24 and the catalyticstructure 40. This gap is necessary for fuel droplets vaporization andproduction of a homogenous mixture ready for reforming on the catalystsurface, and to control temperature of the catalyst. The length of thereaction extension region gap should be greater than 1 cm, andpreferably greater than 10 cm. In order to achieve higher productivityof output hydrogen rich gas 50, it is possible to inject additionalfuel/air mixture 16 into the reaction extension region 32.

FIG. 2 is a cross-sectional view of an embodiment of the plasmatron fuelconverter 10 showing the addition of a fuel/air mixture by injectioninto the plasma discharge volume between electrodes 20, 24. In thisvariant of the invention, all fuel is vaporized and then introduced as afuel/air vapor mixture 16 into the discharge region 26 through the sideopening 28 between the electrodes 20, 24. This embodiment could also beused for gaseous hydrocarbon fuels reformation. Thus, the injection ofthe fuel/air mixture 16 can provide the reactive mixture while alsoshaping the plasma discharge.

FIG. 3 is a cross-sectional view of an embodiment of the plasmatron fuelconverter 10 showing the use of a turbulizer 42 to shorten start-up timeand increase the heat and mass transfer capacity of the reactor 30. Theturbulizer 42 deflects the hot, ignited fuel/air stream 29 coming fromthe bottom electrode 24 to the cold walls of the reactor 30. By heatingthe cold walls with the ignited fuel/air stream 29, the temperaturegradient across the reactor is decreased resulting in increasedefficiency and a faster start-up time. Also, the turbulizer's 42 hotsurface helps to vaporize any remaining liquid fuel droplets in theignited fuel/air stream 29. In a preferred embodiment, the turbulizer 42is made of steel.

FIG. 4 is a cross-sectional view of an embodiment of the plasmatron fuelconverter 10 in which, to further decrease the start up time, part ofthe hot hydrogen rich gas 50 reformate output from the plasmatron isrecirculated back into the plasmatron 10, potentially premixed with theplasma shaping air 19. In other embodiments, the recirculated hydrogenrich gas ouput may be mixed with the fuel/air mixture. Hydrogen rich gas50 recirculation increases the ease of the reforming operation, due tothe much greater volumetric ignition rate (‘flame speed’) of thehydrogen. In this configuration, the equilibrium of the reformats is notchanged, but the kinetics of the partial oxidation reaction could bedramatically increased. The hot recirculated hydrogen rich gas 50 canalso help in quickly raising the temperature needed for start-up.

FIG. 5 is a cross-sectional view of an embodiment of the plasmatron fuelconverter 10 wherein following the fast start period, the energyconsumption could be decreased by using a heat exchanger 44 to preheatthe plasma shaping air 19. In other embodiments, the heat exchanger maybe used to preheat the air 14, the fuel 12, and the fuel/air mixture 16.The heat exchanger 44 allows for decreasing the temperature of thehydrogen rich gas 50 injected into an engine's inlet manifold. Also bypreheating air 14 in the counter flow heat exchanger 44 it is possibleto decrease power of plasmatron necessary to reform the fuel 12 at agiven fuel flow rate. Alternatively at a constant level of plasmatronpower the heat exchanger 44 makes it possible to reform a higher flowrate of fuel 12.

It is recognized that selection of various geometries of electrodeconfigurations and various geometries of introducing fuel and air intothe plasma discharge volume will provide various conversion efficienciesand chemical selectivity. Without limitation, embodiments of alternativeelectrode configurations include: two parallel ring electrodes with agap disposed between; two parallel rod electrodes with a gap disposedbetween; and a first cylindrical electrode co-axially disposed in asecond cylindrical electrode which has a cylindrical inner bore ofgreater diameter than the outer diameter of the first electrode.

FIGS. 6A-6C are cross-sectional views of multiple electrodeconfigurations according to multiple embodiments of the invention. FIG.6A illustrates the use of ring electrodes 60 and 62 positioned in avertical configuration. Fuel or fuel/oxidant mixture 16 is injected fromnozzle 21 through the top ring electrode 60 and into the plasmadischarge volume 26 defined by top and bottom ring electrodes 60 and 62where the electrodes supply a voltage to generate the plasma discharge.The electrodes 60 and 62 are electrically separated by insulator 22.Plasma shaping air 19 is injected from one or more apertures 28 whichmay be located at multiple circumferential positions.

FIG. 6B illustrates a rod-to-rod electrode configuration in which therod electrodes 64 and 66 are positioned in a horizontal configuration.The operation of the system is generally similar to that of otherembodiments in that a fuel/air mixture 16 is injected from a nozzle 21into the plasma discharge volume 26. The electrodes supply voltage togenerate the plasma discharge that is shaped by plasma shaping air 19injected from one or more injection apertures 28.

FIG. 6C illustrates a dual co-axial cylinder configuration in which theinner cylindrical (or conic shaped) electrode 68 has an smaller diameterthan the outer cylindrical electrode 70. In the case of liquidhydrocarbons, it is necessary to configure the nozzle 21 to deliver ahollow spray of fuel or fuel/air mixture 16 into the plasma dischargevolume 26 between the electrodes 68 and 70 to prevent deposition andcoagulation of the fuel/air mixture droplets on the electrodes. Theelectrodes supply voltage to generate the plasma discharge that isshaped by plasma shaping air 19 injected from one or more injectionapertures 28.

Other embodiments of the invention will be apparent to those skilled inthe art from a consideration of the specification or practice of theinvention disclosed herein. It is intended that the specification andexamples be considered as exemplary only, with the true scope and spiritof the invention being indicated by the following claims.

1. A plasmatron fuel converter for producing a hydrogen rich gas,comprising: a first electrode comprising an electrically conductivestructure; a second electrode disposed with respect to the firstelectrode as to create at least two boundaries of a plasma dischargevolume; a power supply connected to the first and second electrodes toprovide voltage and current sufficient to generate a plasma dischargewithin the plasma discharge volume to initiate a reaction of an injectedreactive mixture; and means for establishing a fluid flow through theplasma discharge volume; wherein the fluid flow continually stretchesand extinguishes the plasma discharge generated within the plasmadischarge volume; and wherein the plasma discharge is continually andsubstantially reestablished randomly across the plasma discharge volume.2. The plasmatron fuel converter of claim 1 wherein generation,extinction and reestablishment of the plasma discharge produces aquasi-continuous plasma discharge that is substantially equallydistributed throughout the plasma discharge volume.
 3. The plasmatronfuel converter of claim 2 wherein the quasi-continuous plasma dischargeinitiates chemical reactions substantially throughout the plasmadischarge volume.
 4. The plasmatron fuel converter of claim 3 whereinthe chemical reactions are partial oxidation reactions selected foroperation between stoichiometric partial oxidation and full combustion.5. The plasmatron fuel converter of claim 1 wherein the plasma dischargeis reestablished after extinction in a time of less than 100nanoseconds.
 6. The plasmatron fuel converter of claim 1 furthercomprising an injection mechanism for injecting said injected reactivemixture into said plasma discharge volume.
 7. The plasmatron fuelconverter of claim 6 wherein said injection mechanism comprises: meansfor providing fuel; means for providing air assist to mix with said fueland to form a fuel/oxidant mixture; and a nozzle for controllinginjection of said fuel/oxidant mixture into said plasma dischargevolume.
 8. The plasmatron fuel converter of claim 6 wherein saidinjection mechanism and said fluid flow are adapted to provide anenlarged volumetric contact of said plasma discharge and said injectedreactive mixture within said plasma discharge volume.
 9. The plasmatronfuel converter of claim 1 wherein a flow direction of said injectedreactive mixture is perpendicular to a flow direction of said fluidflow.
 10. The plasmatron fuel converter of claim 1 wherein said injectedreactive mixture and said fluid flow are the same flow.
 11. Theplasmatron fuel converter of claim 1 wherein the fluid flow comprises anoxidant.
 12. The plasmatron fuel converter of claim 11 wherein theoxidant comprises air.
 13. The plasmatron fuel converter of claim 11wherein the oxidant comprises an exhaust gas containing free oxygen. 14.The plasmatron fuel converter of claim 1 wherein the fluid flowcomprises a fuel/oxidant mixture.
 15. The plasmatron fuel converter ofclaim 1 wherein said injected reactive mixture comprises a fuel/oxidantmixture.
 16. The plasmatron fuel converter of claim 1 wherein saidinjected reactive mixture comprises fuel.
 17. The plasmatron fuelconverter of claim 1 wherein the current provided by the power supply islimited so as to prevent non-arcing-to-arc breakdown.
 18. The plasmatronfuel converter of claim 1 wherein said power supply is an adjustablefrequency power supply.
 19. The plasmatron fuel converter of claim 18wherein said adjustable frequency power supply is adapted to be adjustedfrom 100 Hz to 2 MHz.
 20. The plasmatron fuel converter of claim 1wherein said power supply provides voltage in the range of approximately300 volts to 60 kilovolts and current in the range of approximately 10milliamperes to 2 amperes to generate said plasma discharge within theplasma discharge volume.
 21. The plasmatron fuel converter of claim 1wherein said first electrode and said second electrode are hollowcylindrical electrodes disposed to form a channel containing the plasmadischarge volume.
 22. The plasmatron fuel converter of claim 1 whereinsaid first electrode and said second electrode are ring electrodespositioned in a vertical configuration.
 23. The plasmatron fuelconverter of claim 1 wherein said first electrode and said secondelectrode are rod electrodes positioned in a horizontal configuration.24. The plasmatron fuel converter of claim 1 wherein said firstelectrode and said second electrode are cylinders positioned in aco-axial configuration.
 25. The plasmatron fuel converter of claim 1wherein the fluid flow is introduced upstream from the plasma dischargevolume.
 26. The plasmatron fuel converter of claim 1 wherein said fluidflow is adapted to provide an enlarged volumetric contact of said plasmadischarge and said injected reactive mixture within said plasmadischarge volume.
 27. The plasmatron fuel converter of claim 1 furthercomprising: a reactor having a reaction extension region adapted toreceive an ignited reactive mixture from said plasma discharge volume.28. The plasmatron fuel converter of claim 27 wherein the reactor is ametallic or ceramic cylinder.
 29. The plasmatron fuel converter of claim27 wherein an interior of the reactor is covered with thermalinsulation.
 30. The plasmatron fuel converter of claim 27 wherein anexterior of the reactor is covered with thermal insulation.
 31. Theplasmatron fuel converter of claim 27 wherein the reaction extensionregion contains a catalytic structure.
 32. The plasmatron fuel converterof claim 31 wherein the catalytic structure is a metallic or ceramichoneycomb catalytic structure.
 33. The plasmatron fuel converter ofclaim 31 wherein the catalytic structure is coated with one or morecatalyst selected from the group consisting of ruthenium, rhodium,cobalt, iron, nickel, palladium, rhenium, osmium, and platinum.
 34. Theplasmatron fuel converter of claim 27 wherein a turbulizer is disposedwithin the reaction extension region to receive and deflect the ignitedreactive mixture exiting the plasma discharge volume.
 35. The plasmatronfuel converter of claim 27 further comprising: a heat exchanger adaptedto receive the hydrogen rich gas output from said reactor.
 36. Theplasmatron fuel converter of claim 35 wherein the heat exchanger isadapted to preheat the injected reactive mixture or said fluid flow. 37.The plasmatron fuel converter of claim 1 wherein the injected reactivemixture is selected for operation between stoichiometric partialoxidation and full oxidation.
 38. The plasmatron fuel converter of claim1 wherein an oxygen to carbon ratio of the injected reactive mixture isbetween 1.2 and 2.0.
 39. The plasmatron fuel converter of claim 1wherein said oxygen to carbon ratio of the reactive mixture is less than1.2.
 40. The plasmatron fuel converter of claim 1 wherein saidplasmatron fuel converter operates at full combustion and wherein anoutput of said plasmatron fuel converter is a hot gas that is no longerhydrogen-rich.